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Perhaloalkylation of Metal Enolates—Unconventional and Versatile
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SYSNO ASEP 0361368 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Perhaloalkylation of Metal Enolates—Unconventional and Versatile Author(s) Amatov, Tynchtyk (UOCHB-X) ORCID
Jahn, Ullrich (UOCHB-X) ORCIDNumber of authors 2 Source Title Angewandte Chemie - International Edition. - : Wiley - ISSN 1433-7851
Roč. 50, č. 20 (2011), s. 4542-4544Number of pages 3 s. Language eng - English Country DE - Germany Keywords electron transfer ; enols ; perhaloalkylation ; radical reactions ; valence tautomerism Subject RIV CC - Organic Chemistry R&D Projects GA203/09/1936 GA ČR - Czech Science Foundation (CSF) CEZ AV0Z40550506 - UOCHB-X (2005-2011) UT WOS 000290663600001 DOI 10.1002/anie.201007672 Annotation Radically unconventional: Natural products with di- and trichloromethyl groups and trifluoromethylated pharmaceuticals and agrochemicials are interesting compounds, often with intriguing properties. These types of compounds can be prepared by the direct perhaloalkylation of carbonyl compounds in which enolate reactivity and radical reactivity are merged. Workplace Institute of Organic Chemistry and Biochemistry Contact asep@uochb.cas.cz ; Kateřina Šperková, Tel.: 232 002 584 ; Jana Procházková, Tel.: 220 183 418 Year of Publishing 2012
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