Monovrstvy na elektrodách jako základ pro modely přírodních membrán

0359938 - ÚFCH JH 2012 RIV CZ cze C - Conference Paper (international conference)
Josypčuk, Bohdan - Mareček, Vladimír
Monovrstvy na elektrodách jako základ pro modely přírodních membrán.
[Monolayers at electrodes as basis for models of natural membranes.]
Sborník přednášek. XXXI. Moderní elektrochemické metody. Ústí nad Labem: BEST servis, 2011 - (Navrátil, T.; Barek, J.), s. 195-199. ISBN 978-80-254-9634-3.
[Moderní elektrochemické metody /31./. Jetřichovice (CZ), 23.05.2011-27.05.2011]
R&D Projects: GA ČR GAP206/11/1638; GA AV ČR IAA400400806; GA MŠMT(CZ) LC06063
Institutional research plan: CEZ:AV0Z40400503
Keywords : monolayer * voltammetry * reductive desorption * amalgam electrodes
Subject RIV: CG - Electrochemistry

Cílem této práce je elektrochemické studium thiolových vrstev na různých amalagámových elektrodách.

Properties of thiol (HS(CH2)10COOH) monolayers were investigated at stationary electrodes based on silver, copper, bismuth and cadmium solid amalgams covered by a mercury meniscus or by a mercury film. For comparison, parallel experiments were performed at a classical hanging mercury drop electrode. Dependences of monolayer parameters on time of electrochemical deposition of thiol and on scan rate were performed. Statistical evaluation of all obtained results has confirmed that solid amalgam electrodes are a convenient tool for research of thiol layers.
Permanent Link: http://hdl.handle.net/11104/0197616