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Experimental and theoretical study of the complexation of the thallium cation with a hexaarylbenzene-based receptor
- 1.0359318 - ÚMCH 2012 RIV AT eng J - Journal Article
Makrlík, E. - Toman, Petr - Vaňura, P. - Rathore, R.
Experimental and theoretical study of the complexation of the thallium cation with a hexaarylbenzene-based receptor.
Monatshefte fur Chemie. Roč. 142, č. 5 (2011), s. 447-451. ISSN 0026-9247. E-ISSN 1434-4475
R&D Projects: GA ČR(CZ) GAP205/10/2280
Institutional research plan: CEZ:AV0Z40500505
Keywords : receptors * macrocycles * complexation
Subject RIV: BM - Solid Matter Physics ; Magnetism
Impact factor: 1.532, year: 2011
From extraction experiments in the two-phase water/nitrobenzene system and γ-activity measurements, the stability constant of a hexaarylbenzene-based receptor. Tl+ complex species dissolved in nitrobenzene saturated with water was determined. By using the quantum-mechanical density functional level of theory calculations, the most probable structure of this complex was derived.
Permanent Link: http://hdl.handle.net/11104/0006439
Number of the records: 1