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Macropolyhedral boron-containing cluster chemistry [S2B16H17](-). A new eighteen-vertex thiaborane anion
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SYSNO ASEP 0357559 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Macropolyhedral boron-containing cluster chemistry [S2B16H17](-). A new eighteen-vertex thiaborane anion Author(s) Carr, MJ. (GB)
Clegg, W. (GB)
Kennedy, J.D. (GB)
Londesborough, Michael Geoffrey Stephen (UACH-T) SAI, RID, ORCID
Kilner, C. A. (GB)Source Title Collection of Czechoslovak Chemical Communications. - : Ústav organické chemie a biochemie AV ČR, v. v. i. - ISSN 0010-0765
Roč. 75, č. 8 (2010), s. 807-812Number of pages 6 s. Language eng - English Country CZ - Czech Republic Keywords borane cluster ; thiaborane ; macropolyhedral Subject RIV CA - Inorganic Chemistry CEZ AV0Z40320502 - UACH-T (2005-2011) UT WOS 000281958400003 DOI 10.1135/cccc2010053 Annotation The novel eighteen-vertex macropolyhedral dithiaborane anion [S2B16H17](-) 1 has been obtained as its [tmndH](+) salt from the reaction of [S2B17H17] 2 and tmnd in solution in the presence of [RhCl2(eta(5)-C5Me5)](2). It has two cluster skeletal electrons more than the three previously reported eighteen-vertex dithiaborane {S2B16} species n-[S2B16H16], n-[S2B16H15](-) and iso-[S2B16H16], and the anion consists structurally of an arachno {SB9} and a nido {B-9} cluster unit fused with two boron atoms in common, and with an endo-to-exo sulfur bridge that also links the two subclusters together. Workplace Institute of Inorganic Chemistry Contact Jana Kroneislová, krone@iic.cas.cz, Tel.: 311 236 931 Year of Publishing 2011
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