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A combined extraction and DFT study on the complexation of the silver cation with dibenzo-18-crown-6
- 1.0356376 - ÚMCH 2011 RIV AT eng J - Journal Article
Makrlík, E. - Toman, Petr - Vaňura, P.
A combined extraction and DFT study on the complexation of the silver cation with dibenzo-18-crown-6.
Monatshefte fur Chemie. Roč. 142, č. 2 (2011), s. 137-140. ISSN 0026-9247. E-ISSN 1434-4475
R&D Projects: GA ČR(CZ) GAP205/10/2280
Institutional research plan: CEZ:AV0Z40500505
Keywords : crown ethers * macrocycles * complexation
Subject RIV: BM - Solid Matter Physics ; Magnetism
Impact factor: 1.532, year: 2011
Extraction experiments in the two-phase water/nitrobenzene system and γ-activity measurements were used to determine the stability constant of the dibenzo-18-crown-6 • Ag+ complex species in nitrobenzene saturated with water. Furthermore, the structure of the resulting complex was derived by means of theoretical calculations at the density functional level.
Permanent Link: http://hdl.handle.net/11104/0006336
Number of the records: 1