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Synthesis of Mono(perfluoroalkyl) Cyclodextrins via Cross Metathesis

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    SYSNO ASEP0355716
    Document TypeJ - Journal Article
    R&D Document TypeJournal Article
    Subsidiary JČlánek ve WOS
    TitleSynthesis of Mono(perfluoroalkyl) Cyclodextrins via Cross Metathesis
    Author(s) Řezanka, M. (CZ)
    Eignerová, Barbara (UOCHB-X)
    Jindřich, J. (CZ)
    Kotora, M. (CZ)
    Number of authors4
    Source TitleEuropean Journal of Organic Chemistry - ISSN 1434-193X
    -, č. 32 (2010), s. 6256-6262
    Number of pages7 s.
    Languageeng - English
    CountryDE - Germany
    Keywordsmetathesis ; cyclodextrins ; fluorine ; alkylation ; amphiphiles
    Subject RIVCC - Organic Chemistry
    R&D ProjectsKAN200200651 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR)
    CEZAV0Z40550506 - UOCHB-X (2005-2011)
    UT WOS000285041500018
    DOI10.1002/ejoc.201000807
    AnnotationRuthenium–carbene complex catalyzed cross metathesis of monoallyl alpha-, beta-, and gamma-cyclodextrins with perfluoroalkylpropenes resulted in the formation of the corresponding perfluoroalkylated cyclodextrins. The reactions proceeded under standard reaction conditions and yielded the desired compounds in reasonable yields. Dynamic light scattering measurements proved the ability of the prepared compounds to aggregate in water solution forming nanoparticles in the range of tens and thousands of nanometers.
    WorkplaceInstitute of Organic Chemistry and Biochemistry
    Contactasep@uochb.cas.cz ; Kateřina Šperková, Tel.: 232 002 584 ; Jana Procházková, Tel.: 220 183 418
    Year of Publishing2011
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