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Synthesis of Mono(perfluoroalkyl) Cyclodextrins via Cross Metathesis
- 1.0355716 - ÚOCHB 2011 RIV DE eng J - Journal Article
Řezanka, M. - Eignerová, Barbara - Jindřich, J. - Kotora, M.
Synthesis of Mono(perfluoroalkyl) Cyclodextrins via Cross Metathesis.
European Journal of Organic Chemistry. -, č. 32 (2010), s. 6256-6262. ISSN 1434-193X. E-ISSN 1099-0690
R&D Projects: GA AV ČR KAN200200651
Institutional research plan: CEZ:AV0Z40550506
Keywords : metathesis * cyclodextrins * fluorine * alkylation * amphiphiles
Subject RIV: CC - Organic Chemistry
Impact factor: 3.206, year: 2010
Ruthenium–carbene complex catalyzed cross metathesis of monoallyl alpha-, beta-, and gamma-cyclodextrins with perfluoroalkylpropenes resulted in the formation of the corresponding perfluoroalkylated cyclodextrins. The reactions proceeded under standard reaction conditions and yielded the desired compounds in reasonable yields. Dynamic light scattering measurements proved the ability of the prepared compounds to aggregate in water solution forming nanoparticles in the range of tens and thousands of nanometers.
Permanent Link: http://hdl.handle.net/11104/0194418
Number of the records: 1