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Synthesis of C-Doped TiO2 Nanoparticles by Novel Sol-Gel Polycondensation of Resorcinol with Formaldehyde for Visible-Light Photocatalysis
- 1.0349150 - ÚACH 2011 RIV US eng J - Journal Article
Neti, R.N. - Misra, R. - Bera, P.K. - Dhodapkar, R. - Bakardjieva, Snejana - Bastl, Zdeněk
Synthesis of C-Doped TiO2 Nanoparticles by Novel Sol-Gel Polycondensation of Resorcinol with Formaldehyde for Visible-Light Photocatalysis.
Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry. Roč. 40, č. 5 (2010), s. 328-332. ISSN 1553-3174. E-ISSN 1553-3182
Institutional research plan: CEZ:AV0Z40320502; CEZ:AV0Z40400503
Keywords : C-doping * chlorophenol * photo activity * titanium dioxide
Subject RIV: CA - Inorganic Chemistry
Impact factor: 0.504, year: 2010
Nanosized C-doped TiO2 was prepared by a new method based on resorcinol-formaldehyde (RF) gel formation in situ during hydrolysis of Ti precursor (TTIP, titanium tetraisopropoxide). XRD, DRS, EDX, SEM and HRTEM results confirmed that the carbon in the sample existed as free carbon (C-C), carbonate carbon (-CO3) and doped into lattice of TiO2(Ti-C), resulting in red shift of optical adsorption edge and band gap narrowing. The photo activity of the C-doped TiO2, tested on 2-chlorophenol, revealed that it was more active under visible light (kvis= 3.50 x 10-3 min-1).
Permanent Link: http://hdl.handle.net/11104/0006079
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