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Dioxygen Reduction by Cobalt(II) Octaethylporphyrin at Liquid vertical bar Liquid Interfaces
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SYSNO ASEP 0348914 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Dioxygen Reduction by Cobalt(II) Octaethylporphyrin at Liquid vertical bar Liquid Interfaces Author(s) Partovi-Nia, R. (CH)
Su, B. (CH)
Méndez, M. A. (CH)
Habermeyer, B. (FR)
Gros, C. P. (FR)
Barbe, J.-M. (FR)
Samec, Zdeněk (UFCH-W) RID, ORCID
Girault, H. H. (CH)Source Title ChemPhysChem. - : Wiley - ISSN 1439-4235
Roč. 11, č. 13 (2010), s. 2979-2984Number of pages 6 s. Language eng - English Country DE - Germany Keywords cobalt ; electrocatalysis ; liquid/liquid interfaces Subject RIV CG - Electrochemistry R&D Projects GA203/07/1257 GA ČR - Czech Science Foundation (CSF) OC 177 GA MŠMT - Ministry of Education, Youth and Sports (MEYS) CEZ AV0Z40400503 - UFCH-W (2005-2011) UT WOS 000282539100034 DOI 10.1002/cphc.201000200 Annotation Oxygen reduction catalyzed by cobalt(II) (2,3,7,8,12,13,17,18-octaethylporphyrin) [Co(OEP)] at soft interfaces is studied by voltammetry and biphasic reactions. When Co(OEP) is present in a solution of 1,2-dichloroethane in contact. With an aqueous acidic solution, oxygen is reduced if the interface is positively polarized (water phase versus organic phase). This reduction reaction is facilitated when an additional electron donor, here ferrocene, is present in excess in the organic phase. Workplace J. Heyrovsky Institute of Physical Chemistry Contact Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Year of Publishing 2011
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