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A study of calixarene self-assembled monolayers on gold metal surfaces
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SYSNO ASEP 0343545 Document Type C - Proceedings Paper (int. conf.) R&D Document Type Conference Paper Title A study of calixarene self-assembled monolayers on gold metal surfaces Author(s) Šustrová, Barbora (UFCH-W)
Mareček, Vladimír (UFCH-W) RID
Štulík, Karel (UFCH-W)Source Title Sborník přednášek. XXX. Moderní elektroanalytické metody. - Ústí nad Labem : BEST servis, 2010 / Navrátil Tomáš ; Barek J. - ISBN 978-80-254-6710-7 Pages s. 172-176 Number of pages 5 s. Action Modern Electroanalytical Methods /30./ Event date 24.05.2010-28.05.2010 VEvent location Jetřichovice Country CZ - Czech Republic Event type EUR Language eng - English Country CZ - Czech Republic Keywords calix[4]arene ; self-assembled monolayer (SAM) ; gold electrode Subject RIV CG - Electrochemistry R&D Projects IAA400400806 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) CEZ AV0Z40400503 - UFCH-W (2005-2011) UT WOS 000283050900039 Annotation Substituted calix[4]arene molecules were self-assembled on the gold disk electrode surface and the structure of the monolayer formed and the electrochemical behavior of the modified electrode were studied. The formation of the calixarene self-assembled monolayer (SAM) conformed to a Langmuir-type adsorption isotherm, The atomic force microscopy measurement results indicated that the calixarene molecules form a stable monolayer on the Au(111) surface and confirmed the cyclic voltammetry results concerning the SAM structure dependence on the solvent used. Impedance measurements demonstrate that the capacity of the modified electrode varies in the presence of ions, depending on their size and shape. Workplace J. Heyrovsky Institute of Physical Chemistry Contact Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Year of Publishing 2011
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