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Carrier Gas Pressure Effect in Homogeneous Nucleation of n-Alcohols

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    SYSNO ASEP0332914
    Document TypeC - Proceedings Paper (int. conf.)
    R&D Document TypeConference Paper
    TitleCarrier Gas Pressure Effect in Homogeneous Nucleation of n-Alcohols
    TitleVliv tlaku nosného plynu na homogenní nukleaci n-alkoholů
    Author(s) Hyvärinen, A-P. (FI)
    Wedekind, J. (ES)
    Brus, David (UCHP-M) RID, SAI, ORCID
    Lihavainen, H. (FI)
    Source TitleBook of Abstracts. - Prague : Orgit, 2009 / Smolík J. ; O'Dowd C. - ISBN 978-80-02-12161-2
    Pagess. 642-645
    Number of pages4 s.
    ActionInternational Conference Nucleation and Atmospheric Aerosols /18./
    Event date10.08.2009-14.08.2009
    VEvent locationPrague
    CountryCZ - Czech Republic
    Event typeWRD
    Languageeng - English
    CountryCZ - Czech Republic
    Keywordshomogeneous nucleation ; pressure-effect ; n-alcohols
    Subject RIVCF - Physical ; Theoretical Chemistry
    CEZAV0Z40720504 - UCHP-M (2005-2011)
    AnnotationAn overview on the gas pressure effect of nucleation rates of n-alcohols is made. The recent experimental results are compared to the theory introduced by Wedekind et all. The theory is able to predict both the negative and positive pressure effects observed in the experiments, as well as the magnitude of the effect. However, the ratio of carrier gas over vapor pressure has to be shifted by a factor of 0.3-3 for a best match between theory and experiment. This correction factor depends on temperature, vapor pressure of the nucleating vapor, and the carrier gas type.
    WorkplaceInstitute of Chemical Process Fundamentals
    ContactEva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227
    Year of Publishing2010
Number of the records: 1  

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