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Acylation of Cyclohexene and 1-Methylcyclohexene Over Zeolites and Mesoporous Molecular Sieves
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SYSNO ASEP 0326729 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Acylation of Cyclohexene and 1-Methylcyclohexene Over Zeolites and Mesoporous Molecular Sieves Author(s) Vitvarová, Dana (UFCH-W) RID
Voláková, Martina (UFCH-W)
Vlk, Josef (UFCH-W)
Čejka, Jiří (UFCH-W) RID, ORCID, SAISource Title Topics in Catalysis. - : Springer - ISSN 1022-5528
Roč. 52, 6-7 (2009), s. 618-626Number of pages 9 s. Language eng - English Country NL - Netherlands Keywords acylation ; cyclohexene ; 1-methylcyclohexene ; molecular sieves Subject RIV CF - Physical ; Theoretical Chemistry R&D Projects GA104/07/0383 GA ČR - Czech Science Foundation (CSF) FT-TA5/005 GA MPO - Ministry of Industry and Trade (MPO) GD203/08/H032 GA ČR - Czech Science Foundation (CSF) CEZ AV0Z40400503 - UFCH-W (2005-2011) UT WOS 000266263000011 DOI 10.1007/s11244-009-9196-2 Annotation Liquid phase Friedel-Crafts acylation of cyclohexene and 1-methylcyclohexene was investigated over zeolites and mesoporous molecular sieves. The effect of the structure and concentration and type of active sites on the conversion and selectivity of cyclohexene and 1-methylcyclohexene was investigated. In addition, the effect of the chain length of acylating agent was studied. Catalytic experiments were carried out at temperature 80 °C and at atmospheric pressure. The highest conversion was reached over zeolite Beta with Si/Al ratio 37.5 (cyclohexene conversion 78.7%, 1-methylcyclohexene conversion 54.1%). It was found that with increasing chain length of the acylating agent cyclohexene as well as 1-methylcyclohexene conversions decrease. No direct relationship between the conversion of cyclohexene or 1-methylcyclohexene and the concentration of Lewis acid sites was found. Workplace J. Heyrovsky Institute of Physical Chemistry Contact Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Year of Publishing 2010
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