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Binary Homogeneous Nucleation in Selected Aqueous
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SYSNO ASEP 0313952 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Binary Homogeneous Nucleation in Selected Aqueous Title Binární homogenní nukleace ve vybranných vodných plynných směsích Author(s) Maršík, František (UT-L) RID, ORCID
Němec, Tomáš (UT-L) RID, ORCID
Hrubý, Jan (UT-L) RID, ORCID
Demo, Pavel (FZU-D) RID, SAI, ORCID
Kožíšek, Zdeněk (FZU-D) RID, ORCID, SAI
Petr, V. (CZ)
Kolovratník, M. (CZ)Source Title Journal of Solution Chemistry. - : Springer - ISSN 0095-9782
Roč. 37, č. 12 (2008), s. 1671-1708Number of pages 38 s. Language eng - English Country US - United States Keywords nucleation ; steam ; theory Subject RIV BJ - Thermodynamics R&D Projects GA101/05/2524 GA ČR - Czech Science Foundation (CSF) KJB400760701 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) 1M06031 GA MŠMT - Ministry of Education, Youth and Sports (MEYS) IBS2076003 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) CEZ AV0Z20760514 - UT-L (2005-2011) AV0Z10100520 - FZU-D (2005-2011) UT WOS 000260510800005 DOI https://doi.org/10.1007/s10953-008-9337-4 Annotation The objective of this article is to give an overview of available experimental techniques and theoretical fundaments of the classical theories of homogeneous binary nucleation.The principles of the experimental setups are reviewed, ranging from low-nucleationrate (<-103 nuclei/(cm3xs)) devices, i.e., thermal-diffusion cloud chamber, expansion chamber, over-nucleation pulse technique, and nozzle flow, to the condensation wave technique which is applied for the fastest nucleation rates (1015 nucleix(cm3xs)-1). The theoretical description is based on the capillary approximation and takes into account the real properties of fluids (liquid mixtures) including the effects of non-equilibrium processes. A very important effect is associated with the surface tension dependence on the concentration of admixtures that can have a serious impact on the value of the nucleus formation energy. Workplace Institute of Thermomechanics Contact Marie Kajprová, kajprova@it.cas.cz, Tel.: 266 053 154 ; Jana Lahovská, jaja@it.cas.cz, Tel.: 266 053 823 Year of Publishing 2009
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