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Testing anionic spacers by SERRS (surface-enhanced resonance Raman scattering) of a cationic free-base porphyrin in systems with laser-ablated Ag colloids

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    SYSNO ASEP0188901
    Document TypeJ - Journal Article
    R&D Document TypeJournal Article
    Subsidiary JOstatní články
    TitleTesting anionic spacers by SERRS (surface-enhanced resonance Raman scattering) of a cationic free-base porphyrin in systems with laser-ablated Ag colloids
    Author(s) Šmejkal, P. (CZ)
    Vlčková, B. (CZ)
    Procházka, M. (CZ)
    Mojzeš, P. (CZ)
    Pfleger, Jiří (UMCH-V) RID
    Source TitleVibrational Spectroscopy. - : Elsevier - ISSN 0924-2031
    Roč. 19, č. 2 (1999), s. 243-247
    Number of pages5 s.
    Languageeng - English
    CountryNL - Netherlands
    Keywordslaser ablation ; porphyrin ; SERRS
    Subject RIVCF - Physical ; Theoretical Chemistry
    R&D ProjectsGA203/97/0259 GA ČR - Czech Science Foundation (CSF)
    GA202/98/P139 GA ČR - Czech Science Foundation (CSF)
    KSK4050111 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR)
    CEZAV0Z4050913 - UMCH-V
    AnnotationThiopheneacetic acid and several thiol-based anionic species were tested as prospective spacers between the surface of Ag colloidal particles and a chromophoric cationic adsorbate. Time evolution of the SERRS signal of a cationic free base porphyrin, 5,10,15,20-tetrakis(1-methzl-4-pyridiniumyl)porphine attached to the surface of laser-ablated Ag colloidal particles modified by adsorption of either 3-thiol-based anionic species was measured on 2 h time-scale and analyzed.
    WorkplaceInstitute of Macromolecular Chemistry
    ContactEva Čechová, cechova@imc.cas.cz ; Tel.: 296 809 358
    Year of Publishing2003

Number of the records: 1  

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