0181598 - UFCH-W 20030025 RIV DE eng J - Journal Article
Hoshino, S. - Higuchi, S. - Fiedler, Jan - Su, Ch. Y. - Knödler, A. - Schwederski, B. - Sarkat, B. - Hartmann, H. - Kaim, W.
Long-Range Electronic Coupling in Various Oxidation States of a C4-Linked Tris (ß-diketonato)ruthenium Dimer.
Angewandte Chemie - International Edition. Roč. 42, č. 6 (2003), s. 674-677. ISSN 1433-7851. E-ISSN 1521-3773
R&D Projects: GA MŠMT OC D15.10
Institutional research plan: CEZ:AV0Z4040901
Keywords : alkynyl ligands * mixed-valent compounds * ruthenium
Subject RIV: CF - Physical ; Theoretical Chemistry
Impact factor: 8.427, year: 2003

Strong electronic coupling over a distance of 1,3 nm is observed for the Ru2 (IV, III) state of the complex 1n (n=+). The fully delocalized system 1+ is distinguished by an extremely intense intervalence charge-transfer (IVCT) band and a single intense vibrational band.
Permanent Link: http://hdl.handle.net/11104/0078141