Number of the records: 1
Redox Activation of Dicarbonyl(.eta.5-Cyclopentadienyl)Methyl Iron within the Cavity of .beta.-Cyclodextrin: Carbon Monoxide Insertion in Iron-Methyl Bond
- 1.
SYSNO ASEP 0181594 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Ostatní články Title Redox Activation of Dicarbonyl(.eta.5-Cyclopentadienyl)Methyl Iron within the Cavity of .beta.-Cyclodextrin: Carbon Monoxide Insertion in Iron-Methyl Bond Author(s) Pospíšil, Lubomír (UFCH-W) RID, ORCID
Hromadová, Magdaléna (UFCH-W) RID, ORCID, SAI
Fiedler, Jan (UFCH-W) RID, ORCID
Amatore, C. (FR)
Verpeaux, J. N. (FR)Source Title Journal of Organometallic Chemistry. - : Elsevier - ISSN 0022-328X
Roč. 668, 1/2 (2003), s. 9-16Number of pages 8 s. Language eng - English Country CH - Switzerland Keywords redox activation ; beta-cyclodextrin ; CO insertion Subject RIV CG - Electrochemistry R&D Projects GP203/02/P082 GA ČR - Czech Science Foundation (CSF) OC D15.10 GA MŠMT - Ministry of Education, Youth and Sports (MEYS) CEZ AV0Z4040901 - UFCH-W Annotation The organometallic complex CpFe(CO)2CH3 is included in a .beta.-cyclodextrin cavity, retains its redox activity and undergoes CO insertion into the methyl-metal bond. The reaction inside the cavity suppresses undesirable loss of released CO from the reaction site. This simplifies the mechanism of the bond-insertion reaction in the presence of cyclodextrin. Further enhancement is observed in presence of free CO, which can penetrate to the reaction site inside the cyclodextrin cavity. Workplace J. Heyrovsky Institute of Physical Chemistry Contact Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Year of Publishing 2004
Number of the records: 1