0181412 - UFCH-W 20020079 RIV CH eng J - Journal Article
Ulmeanu, S. M. - Jensen, H. - Samec, Zdeněk - Bouchard, G. - Carrupt, P. A. - Giraut, H. H.
Cyclic Voltammetry of Highly Hydrophilic Ions at a Supported Liquid Membrane.
Journal of the Electroanalytical Chemistry and Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. Roč. 530, 1/2 (2002), s. 10-15. ISSN 0022-0728
R&D Projects: GA AV ČR IAA4040902
Institutional research plan: CEZ:AV0Z4040901
Keywords : liquid-liquid interface * membrane * cyclic voltammetry
Subject RIV: CG - Electrochemistry
Impact factor: 2.027, year: 2002

Cyclic voltammetry was used to study the coupling of ion transfer reactions at a liquid membrane. Liquid are either supported by a porous hydrophobic membrane or are merely a free standing organic solvent layer comprised between two hydrophilic dialysis membranes supporting the adjacent aqueous phases. This new methodology opens a way to measure the Gibbs energy of tranfer of highly hydrophilic or hydrophobic ions.
Permanent Link: http://hdl.handle.net/11104/0077986