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MCM-41-Immobilized [Rh(cod)OCH3]2 Complex - a Hybrid Catalyst for the Polymerization of Phenylacetylene and Its Ring-Substituted Derivatives
- 1.0181387 - UFCH-W 20020051 RIV CH eng J - Journal Article
Balcar, Hynek - Sedláček, J. - Čejka, Jiří - Vohlídal, J.
MCM-41-Immobilized [Rh(cod)OCH3]2 Complex - a Hybrid Catalyst for the Polymerization of Phenylacetylene and Its Ring-Substituted Derivatives.
Macromolecular Rapid Communications. Roč. 23, č. 1 (2002), s. 32-37. ISSN 1022-1336. E-ISSN 1521-3927
R&D Projects: GA ČR GA202/00/1152
Institutional research plan: CEZ:AV0Z4040901
Keywords : hybrid catalyst * organometallic catalysts * polyacetylenes
Subject RIV: CF - Physical ; Theoretical Chemistry
Impact factor: 2.901, year: 2002
The immobilization of [Rh(cod)OCH3]2 on mesoporous molecular sieves MCM-41 provides the first inorganic-type hybrid catalyst, which affords heterogeneous polymerization of phenylacetylene and its ring-substituted derivatives into readily isolable high-molecular-weight (Mw from 50 000 to 180 000) substituted polyvinylenes of high cis-transoid structure.
Permanent Link: http://hdl.handle.net/11104/0077968
Number of the records: 1