0181359 - UFCH-W 20020014 RIV US eng J - Journal Article
Amano, T. - Zelinger, Zdeněk
Submillimeter-wave Spectroscopy of HNC Produced in an Extended Negative Glow Discharge.
Journal of Molecular Spectroscopy. Roč. 211, - (2002), s. 273-278. ISSN 0022-2852. E-ISSN 1096-083X
R&D Projects: GA MŠMT OC 715.50
Institutional research plan: CEZ:AV0Z4040901
Keywords : hydrogen isocyanide * microwave spectroscopy * extended negative glow discharge
Subject RIV: CF - Physical ; Theoretical Chemistry
Impact factor: 1.251, year: 2002

Submillimeter-wave transitions of HNC are observed in an extended negative glow discharge. The measurements of the rotational lines in the ground state as well as in the vibrational fundamentals are extended to higher J values. The lines in the higher vibrational excited states are also observed and assigned, using frequency-magnetic field double modulation technique. Dramatic enhancement of the signal intensity strongly suggests that HNC predominantly produced in the extended negative glow discharge through the dissociative recombination reaction of HCNH+ with electrons.
Permanent Link: http://hdl.handle.net/11104/0077941