A Fully Characterized Complex Ion with Unreduced TCNQ as Fourfold Bridging Ligand: [(ć.sub.4./sub.-TCNQ){fac-Re(CO).sub.3./sub.(bpy)}.sub.4./sub.].sup.4+./sup..

0181268 - UFCH-W 20010186 RIV DE eng J - Journal Article
Hartmann, H. - Kaim, W. - Hartenbach, I. - Schleid, T. - Wanner, M. - Fiedler, Jan
A Fully Characterized Complex Ion with Unreduced TCNQ as Fourfold Bridging Ligand: [(ć₄-TCNQ){fac-Re(CO)₃(bpy)}₄]⁴⁺.
Angewandte Chemie - International Edition. Roč. 40, č. 15 (2001), s. 2842-2844. ISSN 1433-7851. E-ISSN 1521-3773
R&D Projects: GA MŠMT OC D15.10
Institutional research plan: CEZ:AV0Z4040901
Keywords : electrochemistry * N ligands * tetranuclear complexes
Subject RIV: CG - Electrochemistry
Impact factor: 8.255, year: 2001

First structurally characterized discrete metal complex with tetranucleating 7,7,8,8-tetracyano-p-quinodimethane (TCNQ) exhibits an innocent behavior of a typical non-innocent ligand. The coordination of four [Re(CO)3(2,2' bipyridine)]+ units strongly facilites the reduction of TCNQ, by 0.74V.
Permanent Link: http://hdl.handle.net/11104/0077851