0181238 - UFCH-W 20010153 RIV CH eng J - Journal Article
Horáček, Michal - Bazyakina, N. - Štěpnička, P. - Gyepes, R. - Císařová, I. - Bredeau, S. - Meunier, P. - Kubišta, Jiří - Mach, Karel
Reactions of Titanocene-Bis(trimethylsilyl)Ethyne Complexes with Diethynylsilane Derivatives.
Journal of Organometallic Chemistry. Roč. 628, č. 1 (2001), s. 30-38. ISSN 0022-328X. E-ISSN 1872-8561
R&D Projects: GA ČR GA203/99/0846
Institutional research plan: CEZ:AV0Z4040901
Keywords : titanocenes * oxidative addition * X-ray crystallography
Subject RIV: CF - Physical ; Theoretical Chemistry
Impact factor: 1.803, year: 2001

Titanocene complexes [Ti(eta5-C5H5-nMen)2(eta2-Me3SiCsCSiMe3)] (n=0,4 and 5) react uniformly with siladiynes R22Si(CsCR1)2, where R1=Ph, and R2=Ph or Me to give the corresponding silacyclobutene-annelated titanacyclobutene complexes, 3-bis(eta5-cyclopentadienyl)titana-6-diorganylsilabicyclo[2.2.0]hexa-1-(2),4(5)-dienes, (eta5-C5H5-nMen)2Ti{R12C4(SiR22)}].
Permanent Link: http://hdl.handle.net/11104/0077822