Ship-in-Bottle Synthesis of Anionic Rh Carbonyls in Faujasites

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SYSNO ASEP	0181122
Document Type	J - Journal Article
R&D Document Type	Journal Article
Subsidiary J	Ostatní články
Title	Ship-in-Bottle Synthesis of Anionic Rh Carbonyls in Faujasites
Author(s)	Brabec, Libor (UFCH-W)_{RID, ORCID} Nováková, Jana (UFCH-W)_RID
Source Title	Journal of Molecular Catalysis A-Chemical. - : Elsevier - ISSN 1381-1169 Roč. 166, č. 2 (2001), s. 283-292
Number of pages	10 s.
Language	eng - English
Country	NL - Netherlands
Keywords	[Rh(NH3)5Cl] in alkali faujasites ; Carbonylation of ; Rh carbonyls of different charges
Subject RIV	CF - Physical ; Theoretical Chemistry
R&D Projects	IAA4040710 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR)
CEZ	AV0Z4040901 - UFCH-W
Annotation	Direct carbonylation of [Rh(NH3)5Cl]2+ in faujasites yields polynuclear anionic Rh carbonyls at 25-100ř, if the water amount is sufficient. The [Rh6(CO)15]2- complex is probable. After dehydration or at 200ř [Rh(CO)2]+ is formed.
Workplace	J. Heyrovsky Institute of Physical Chemistry
Contact	Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196
Year of Publishing	2002

Number of the records: 1