0181122 - UFCH-W 20010029 RIV NL eng J - Journal Article
Brabec, Libor - Nováková, Jana
Ship-in-Bottle Synthesis of Anionic Rh Carbonyls in Faujasites.
Journal of Molecular Catalysis A-Chemical. Roč. 166, č. 2 (2001), s. 283-292. ISSN 1381-1169. E-ISSN 1873-314X
R&D Projects: GA AV ČR IAA4040710
Institutional research plan: CEZ:AV0Z4040901
Keywords : [Rh(NH3)5Cl] in alkali faujasites * Carbonylation of * Rh carbonyls of different charges
Subject RIV: CF - Physical ; Theoretical Chemistry
Impact factor: 1.520, year: 2001

Direct carbonylation of [Rh(NH3)5Cl]2+ in faujasites yields polynuclear anionic Rh carbonyls at 25-100ř, if the water amount is sufficient. The [Rh6(CO)15]2- complex is probable. After dehydration or at 200ř [Rh(CO)2]+ is formed.
Permanent Link: http://hdl.handle.net/11104/0077719