Number of the records: 1
Geometrical and Electronic Structures of the Acetyl Complex Re(bpy)(CO).sub.3./sub.(COCH.sub.3./sub.) and of [M(bpy)(CO).sub.4./sub.](OTf), M=Mn, Re
- 1.
SYSNO ASEP 0181037 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Ostatní články Title Geometrical and Electronic Structures of the Acetyl Complex Re(bpy)(CO)3(COCH3) and of [M(bpy)(CO)4](OTf), M=Mn, Re Author(s) Scheiring, T. (DE)
Kaim, W. (DE)
Fiedler, Jan (UFCH-W) RID, ORCIDSource Title Journal of Organometallic Chemistry. - : Elsevier - ISSN 0022-328X
Roč. 598, č. 1 (2000), s. 136-141Language eng - English Country CH - Switzerland Subject RIV CF - Physical ; Theoretical Chemistry CF - Physical ; Theoretical Chemistry R&D Projects OC D14.20 GA MŠMT - Ministry of Education, Youth and Sports (MEYS) CEZ AV0Z4040901 - UFCH-W A54/98:Z4-040-9-ii Annotation The title compounds has been investigated by infrared spectroelectrochemistry to reveal the occupation of the pi*(bpy)MO on one-electron reduction to radical-anion with negligible participation of the pi-accepting acetyl group.Crystal structure analysis of Re(bpy)(CO) 3 (COCH 3 ) revealed a short C-O(acetyl) and long Re-C(acetyl) bond and an orientation of the Re-C(O)CH 3 plane parallel to C 2 axis of coordinated bpy. Workplace J. Heyrovsky Institute of Physical Chemistry Contact Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Year of Publishing 2001
Number of the records: 1