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Geometrical and Electronic Structures of the Acetyl Complex Re(bpy)(CO).sub.3./sub.(COCH.sub.3./sub.) and of [M(bpy)(CO).sub.4./sub.](OTf), M=Mn, Re
- 1.0181037 - UFCH-W 20000208 RIV CH eng J - Journal Article
Scheiring, T. - Kaim, W. - Fiedler, Jan
Geometrical and Electronic Structures of the Acetyl Complex Re(bpy)(CO)3(COCH3) and of [M(bpy)(CO)4](OTf), M=Mn, Re.
Journal of Organometallic Chemistry. Roč. 598, č. 1 (2000), s. 136-141. ISSN 0022-328X. E-ISSN 1872-8561
R&D Projects: GA MŠMT OC D14.20
Institutional research plan: CEZ:AV0Z4040901; CEZ:A54/98:Z4-040-9-ii
Subject RIV: CF - Physical ; Theoretical Chemistry
Impact factor: 1.632, year: 2000
The title compounds has been investigated by infrared spectroelectrochemistry to reveal the occupation of the pi*(bpy)MO on one-electron reduction to radical-anion with negligible participation of the pi-accepting acetyl group.
Permanent Link: http://hdl.handle.net/11104/0077645
Number of the records: 1