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Competitive Association and Charge Transfer in the Reactions of NO + with some Ketones: a Select Ion Flow Drift Tube Study
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SYSNO ASEP 0181007 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Ostatní články Title Competitive Association and Charge Transfer in the Reactions of NO + with some Ketones: a Select Ion Flow Drift Tube Study Author(s) Fairley, D. A. (NZ)
Milligan, D. B. (NZ)
Freeman, C. G. (NZ)
McEwan, M. J. (NZ)
Španěl, Patrik (UFCH-W) RID, ORCID
Smith, D. (GB)Source Title International Journal of Mass Spectrometry. - : Elsevier - ISSN 1387-3806
Roč. 193, č. 1 (1999), s. 35-43Language eng - English Country NL - Netherlands Keywords ion-molecule reaction kinetics ; selected ion flow drift tube ; ternary association Subject RIV CF - Physical ; Theoretical Chemistry CF - Physical ; Theoretical Chemistry CEZ A54/98:Z4-040-9-ii Annotation The rate coefficients and product ion branching rations have been determined for reactions between NO+ and three ketones, acetone, 2-butanone, and 3-pentanone, as a function of NO+ reactant ketone centre-of-mass- energy and NO+ helium carrier gas atom centre-of-mass energy in a flowing afterglow selected ion flow drift tube apparatus at a temperature of 300K. Ternary asociation was the dominant channel at low energys and charge transfer occured at higher energy. Workplace J. Heyrovsky Institute of Physical Chemistry Contact Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Year of Publishing 2001
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