Electrochemical Reductions of Methyl Azinyl Ketoximes on Mercury

Number of the records: 1

SYSNO ASEP	0180993
Document Type	J - Journal Article
R&D Document Type	Journal Article
Subsidiary J	Ostatní články
Title	Electrochemical Reductions of Methyl Azinyl Ketoximes on Mercury
Author(s)	Cibulka, R. (CZ) Liška, F. (CZ) Ludvík, Jiří (UFCH-W)_{RID, ORCID}
Source Title	Collection of Czechoslovak Chemical Communications. - : Ústav organické chemie a biochemie AV ČR, v. v. i. - ISSN 0010-0765 Roč. 65, č. 10 (2000), s. 1630-1642
Language	eng - English
Country	CZ - Czech Republic
Subject RIV	CG - Electrochemistry CG - Electrochemistry
R&D Projects	GA203/99/0763 GA ČR - Czech Science Foundation (CSF)
CEZ	AV0Z4040901 - UFCH-W
	A54/98:Z4-040-9-ii
Annotation	Electroreductions of hydroxyimino group of methyl hetaryl ketoximes on mercury electrodes were studied using dc polarography, coulometry and preparative electrolysis.Depending on pH, double-protonated, single-protonated and neutral forms of the ketoximes are transformed in a four-electron reduction to the corresponding amine.Reducibility of the oximes correlates with the enhancement of their hydrolytic activity towards 4-nitrophenyl acetate.
Workplace	J. Heyrovsky Institute of Physical Chemistry
Contact	Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196
Year of Publishing	2001

Number of the records: 1