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Orientation Dependence of Charge-Transfer Processes on TiO.sub.2./sub. (Anatase) Single Crystals

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    SYSNO ASEP0180872
    Document TypeJ - Journal Article
    R&D Document TypeJournal Article
    Subsidiary JOstatní články
    TitleOrientation Dependence of Charge-Transfer Processes on TiO2 (Anatase) Single Crystals
    Author(s) Hengerer, R. (CH)
    Kavan, Ladislav (UFCH-W) RID, ORCID
    Krtil, Petr (UFCH-W) RID, ORCID
    Grätzel, M. (CH)
    Source TitleJournal of the Electrochemical Society. - : Electrochemical Society - ISSN 0013-4651
    Roč. 147, č. 4 (2000), s. 1467-1472
    Languageeng - English
    CountryUS - United States
    Subject RIVCG - Electrochemistry CG - Electrochemistry
    R&D ProjectsIAA4040804 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR)
    OC D14.10 GA MŠMT - Ministry of Education, Youth and Sports (MEYS)
    KSK2040602 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR)
    CEZAV0Z4040901 - UFCH-W
    AnnotationElectrochemical measurements in aqueous and aprotic media have been carried out on anatase single crystals with exposed (101) and (001) surfaces, respectively.Water reduction and photooxidation take place at more negative potentials for the (001) surface than for the (101) surface.This can be rationalized in terms of a more negative flatband potential (by ca. 60 mV) for the (001)face. Lithium insertion is favored on the (001) face.
    WorkplaceJ. Heyrovsky Institute of Physical Chemistry
    ContactMichaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196
    Year of Publishing2001

Number of the records: 1  

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