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[N,N'-Bis(3-aminopropyl)ethylenediamine-kappa4N,N',N",N"'](trithiocyanurato-kappa2N,S)zinc(II) ethanol solvate

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    SYSNO ASEP0172392
    Document TypeJ - Journal Article
    R&D Document TypeJournal Article
    Subsidiary JOstatní články
    Title[N,N'-Bis(3-aminopropyl)ethylenediamine-kappa4N,N',N",N"'](trithiocyanurato-kappa2N,S)zinc(II) ethanol solvate
    Author(s) Marek, J. (CZ)
    Kopel, P. (CZ)
    Trávníček, Zdeněk (UEB-Q)
    Source TitleActa Crystallographica Section C-Crystal Structure Communications. - : Wiley - ISSN 0108-2701
    Roč. 59, č. 12 (2003), s. 558-560
    Number of pages3 s.
    Languageeng - English
    CountryDE - Germany
    Keywordscrystal structure ; bidentate ligand ; hydrogen bonds
    Subject RIVCE - Biochemistry
    R&D ProjectsGA203/00/0152 GA ČR - Czech Science Foundation (CSF)
    CEZAV0Z5038910 - UEB-Q
    AnnotationIn the crystal structure of the title compound, [N,N'-bis(3-aminopropyl)ethylenediamine-kappa(4)N,N',N",N"'][1,3,5-triazine-2,4,6(1H,3H,5H)-trithionato(2-)-kappa(2)N,S]zinc(II) ethanol solvate, [Zn(C(8)H(22)N(4))(2)(C(3)HN(3)S(3))].C(2)H(6)O, the Zn(II) atom is octahedrally coordinated by four N atoms [Zn-N = 2.104 (2)-2.203 (2) A] of a tetradentate N-donor N,N'-bis(3-aminopropyl)ethylenediamine (bapen) ligand and by two S and N atoms [Zn-S = 2.5700 (7) A and Zn-N = 2.313 (2) A] of a trithiocyanurate(2-) (ttcH(2-)) dianion bonded as a bidentate ligand in a cis configuration. The crystal structure of the compound is stabilized by a network of hydrogen bonds.
    WorkplaceInstitute of Experimental Botany
    ContactDavid Klier, knihovna@ueb.cas.cz, Tel.: 220 390 469
    Year of Publishing2004

Number of the records: 1  

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