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Infinite-dilution partial molar properties of naphthalene and biphenyl in carbon dioxide from supercritical fluid chromatography: composition effects in the stationary phase

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    SYSNO ASEP0162198
    Document TypeJ - Journal Article
    R&D Document TypeJournal Article
    Subsidiary JOstatní články
    TitleInfinite-dilution partial molar properties of naphthalene and biphenyl in carbon dioxide from supercritical fluid chromatography: composition effects in the stationary phase
    Author(s) Jeon, Y. P. (KP)
    Roth, Michal (UIACH-O) RID, ORCID
    Kwon, Y. J. (KP)
    Source TitleJournal of Physical Chemistry A. - : American Chemical Society - ISSN 1089-5639
    Roč. 104, č. 55 (2000), s. 5396-5400
    Number of pages5 s.
    Languageeng - English
    CountryUS - United States
    Subject RIVCE - Biochemistry
    R&D ProjectsGA203/98/0635 GA ČR - Czech Science Foundation (CSF)
    AnnotationThe temperature and pressure effects on retention of naphthalene and biphenyl in supercritical fluid chromatography were investigated within 35-70 oC and 7.5-15 MPa. The retention factors were used to derive the infinite-dilution partial molar volumes of the two solutes in supercritical carbon dioxide, the infinite/dilution molar volumes of the two solutes in supercritical carbon dioxide, the infinite- dilution molar enthalpies of transfer of the two solutes from the stationary phase to supercritical CO2, and some quantities measuring short-range interactions between CO2 and the solutes.
    WorkplaceInstitute of Analytical Chemistry
    ContactIveta Drobníková, drobnikova@iach.cz, Tel.: 532 290 234
    Year of Publishing2001

Number of the records: 1  

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