0102478 - FZU-D 20040529 RIV DK eng J - Journal Article
Fábry, Jan - Dušek, Michal - Fejfarová, Karla - Krupková, Radmila - Vaněk, Přemysl - Němec, I.
Two phases of bis(tetraethylammonium) di-.mu.-chloro-bis[dichloropalladium(II)].
[Dvě fáze komplexu bis(tetraethylammonium) di-.mu.-chloro-bis[dichloropalladium(II)].]
Acta Crystallographica Section C-Crystal Structure Communications. C60, - (2004), m426-m430. ISSN 0108-2701. E-ISSN 2053-2296
R&D Projects: GA ČR GA203/02/0436
Institutional research plan: CEZ:AV0Z1010914
Keywords : single X-ray study * vibrational spectroscopy * C-H...Cl hydrogen bonds * phase transition
Subject RIV: CC - Organic Chemistry
Impact factor: 0.728, year: 2004

A phase transition was found to occur at "153 K in the title compound, (C₈H_{2 0}N)₂[Pd₂Cl₆]. The structures of the two phases are reported at 292 and 130 K. The low-temperature phase is twinned. There are C-H...Cl interactions as short as ~2.80 A°, indicating the existence of hydrogen bonds, and this was confirmed by vibrational spectroscopy

Struktura dvou fází (C₈H_{2 0}N)₂[Pd₂Cl₆] je popsána pro teplotu 292 a 130 K. Nízkoteplotní fáze je zdvojčatělá
Permanent Link: http://hdl.handle.net/11104/0009826