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Chemical vapour generation of silver: reduced palladium as permanent reaction modifier for enhanced performance
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SYSNO ASEP 0102262 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Ostatní články Title Chemical vapour generation of silver: reduced palladium as permanent reaction modifier for enhanced performance Title Chemické generování par stříbra: redukované paladium jako permanentní reakční modifikátor pro zlepšení charakteristik generátoru Author(s) Matoušek, Tomáš (UIACH-O) RID, ORCID
Sturgeon, R. E. (CA)Source Title Journal of Analytical Atomic Spectrometry. - : Royal Society of Chemistry - ISSN 0267-9477
Roč. 19, č. 8 (2004), s. 1014-1017Number of pages 4 s. Language eng - English Country GB - United Kingdom Keywords chemical vapour generation ; chemical modification ; silver Subject RIV CB - Analytical Chemistry, Separation R&D Projects GA203/01/0453 GA ČR - Czech Science Foundation (CSF) CEZ AV0Z4031919 - UIACH-O Annotation Permanent modification of the surface of a continuous flow system by reduced metals was studied for chemical vapour generation of silver. Both nickel and palladium were found active. A possible mechanism responsible for improvement is proposed; the modifier catalyses the reaction of residual NaBH4 in the reaction mixture, necessary for the final phases of volatile compound formation and/or its release from solution Workplace Institute of Analytical Chemistry Contact Iveta Drobníková, drobnikova@iach.cz, Tel.: 532 290 234 Year of Publishing 2005
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