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Macropolyhedral boron-containing cluster chemistry. Cluster opening and B-frame rearrangement in the reaction of B16H20 with [{(IrCl2(eta(5)-C5Me5)}(2)]. Synchrotron X-ray structures of [(eta(5)-C5Me5)(2)Ir2B16H17Cl] and [(eta(5)-C5Me5)(2)Ir2B16H15Cl]
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SYSNO ASEP 0050894 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Ostatní články Title Macropolyhedral boron-containing cluster chemistry. Cluster opening and B-frame rearrangement in the reaction of B16H20 with [{(IrCl2(eta(5)-C5Me5)}(2)]. Synchrotron X-ray structures of [(eta(5)-C5Me5)(2)Ir2B16H17Cl] and [(eta(5)-C5Me5)(2)Ir2B16H15Cl] Title Macropolyedrická borová klastrová chemie. Otevření klastru a přesmyk B-skeletu při reakci B16H20 s [{(IrCl2(eta(5)-C5Me5)}(2)].Synchrotronové rentgenové struktury [(eta(5)-C5Me5)(2)Ir2B16H17Cl] a [(eta(5)-C5Me5)(2)Ir2B16H15Cl] Author(s) Carr, MJ. (GB)
Perera, SD. (LK)
Jelínek, Tomáš (UACH-T)
Kilner, C. A. (GB)
Clegg, W. (GB)
Štíbr, Bohumil (UACH-T) RID, SAI, ORCID
Kennedy, J.D. (GB)Source Title Dalton Transactions. - : Royal Society of Chemistry - ISSN 1477-9226
Roč. 44, - (2006), s. 5221-5224Number of pages 5 s. Language eng - English Country GB - United Kingdom Keywords intercluster bonding intimagy ; matallaborane clusters ; crystal-structures Subject RIV CA - Inorganic Chemistry R&D Projects IAA400320601 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) GA203/05/2646 GA ČR - Czech Science Foundation (CSF) CEZ AV0Z40320502 - UACH-T (2005-2011) Annotation Products from the reaction of + nido ten- vertex : nido eight-vertex, B16H20 1 with [{( IrCl2(eta(5)- C5Me5)} (2)] and tmnd show unanticipated rearrangement of the starting {B-16} skeleton, as exhibited by + nido ten- vertex : nido ten- vertex, [(eta(5)- C5Me5) (2) Ir2B16H17Cl] 2 which has a {B-2} edge conjunction and by + nido ten- vertex : nido eleven- vertex, [(eta(5)- C5Me5) 2Ir2B16H15Cl] 3 which has a {B-3} face conjunction. Workplace Institute of Inorganic Chemistry Contact Jana Kroneislová, krone@iic.cas.cz, Tel.: 311 236 931 Year of Publishing 2007
Number of the records: 1