Silver(I) thiosemicarbazone complex [Ag(catsc)(PPh.sub.3./sub.).sub.2./sub.]NO.sub.3./sub.: synthesis, characterization, crystal structure and antibacterial study

0510469 - FZÚ 2020 RIV FR eng J - Journal Article
Khalaji, A.D. - Shahsavani, E. - Feizi, N. - Kučeráková, Monika - Dušek, Michal - Mazandarani, R.
Silver(I) thiosemicarbazone complex [Ag(catsc)(PPh₃)₂]NO₃: synthesis, characterization, crystal structure and antibacterial study.
Comptes Rendus Chimie. Roč. 20, č. 5 (2017), s. 534-539. ISSN 1631-0748. E-ISSN 1878-1543
R&D Projects: GA MŠMT(CZ) LO1603
EU Projects: European Commission(CZ) CZ.2.16/3.1.00/24510
Institutional support: RVO:68378271
Keywords : silver(I) complex * single-crystal * antibacterial effect * tetrahedral * bidentate
OECD category: Condensed matter physics (including formerly solid state physics, supercond.)
Impact factor: 1.877, year: 2017
Method of publishing: Limited access
https://doi.org/10.1016/j.crci.2016.09.001

We report the synthesis, characterization and crystal structure of a new mononuclear silver(I) complex, [Ag(catsc)(PPh3)2]NO3(catsc = 3-phenylpropenalthiosemicarbazone). The complex was prepared by the reaction of catsc and AgNO3 in the presence of PPh3 and characterized by elemental analysis, FTIR, 1H, 13C and 31P NMR spectroscopy, and single-crystal X-ray diffraction. In the complex, catsc acts as a bidentate NS ligand while the nitrate is a counter ion. The silver ion is coordinated by a bidentate ligand and two PPh3 in the form of a distorted tetrahedron. In addition, the antibacterial effe ct of the complex was studied against the standard strains of two gram-positive and two gram-negative bacteria.

Permanent Link: http://hdl.handle.net/11104/0300943