Crystal structure of NaCd(H.sub.2./sub.PO.sub.3./sub.).sub.3./sub..H.sub.2./sub.O and spectroscopic study of NaM(H.sub.2./sub.PO.sub.3./sub.).sub.3./sub..H.sub.2./sub.O, M = Mn, Co, Ni, Zn, Mg and Cd

0458862 - FZÚ 2017 RIV GB eng J - Journal Article
Ouarsal, R. - Lachkar, M. - Dušek, Michal - Albert, E.B. - Castelló, J.B.C. - El Bali, B.
Crystal structure of NaCd(H₂PO₃)₃.H₂O and spectroscopic study of NaM(H₂PO₃)₃.H₂O, M = Mn, Co, Ni, Zn, Mg and Cd.
Polyhedron. Roč. 106, Feb (2016), s. 132-137. ISSN 0277-5387. E-ISSN 1873-3719
Grant - others:AV ČR(CZ) AP0701
Program: Akademická prémie - Praemium Academiae
Institutional support: RVO:68378271
Keywords : transition metal * phosphite * crystal structure * spectroscopy * d-d transitions
Subject RIV: BM - Solid Matter Physics ; Magnetism
Impact factor: 1.926, year: 2016

NaCd(H2PO3)3.H2O was synthesized in solution and its structure was studied by single-crystal X-ray diffraction. It belongs the series of isostructural phosphites NaM(H2PO3)3.H2O (M = Mn, Co, Ni, Zn and Mg). IR spectroscopic studies show the bands confirming the presence of the phosphite H2PO3 anion in the whole series NaM(H2PO3)3.H2O, M = Mn, Co, Ni, Zn, Mg and Cd. The UV–Vis spectroscopy was used for characterizing the d–d transitions in the Mn, Co and Ni phosphites.

Permanent Link: http://hdl.handle.net/11104/0259085