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UV Laser-Induced Photolysis of Diethyl Selenium and Diethyl Tellurium: Extrussion of Selenium and Tellurium via Molecular Elimination of Ethene

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    0166233 - UCHP-M 20013089 RIV US eng J - Journal Article
    Pola, Josef - Ouchi, A.
    UV Laser-Induced Photolysis of Diethyl Selenium and Diethyl Tellurium: Extrussion of Selenium and Tellurium via Molecular Elimination of Ethene.
    Journal of Organometallic Chemistry. Roč. 629, 1-2 (2001), s. 93-96. ISSN 0022-328X. E-ISSN 1872-8561
    R&D Projects: GA AV ČR IAA4072107
    Keywords : diethyl selenium * laser photolysis * molecular mechanism
    Subject RIV: CH - Nuclear ; Quantum Chemistry
    Impact factor: 1.803, year: 2001

    KrF laser-induced photolysis of gaseous (C2H5)(2)M (M = Se, Te) compounds is shown to be a one-photon process controlled by the cleavage of both C-M bonds. It is dominated by the molecular elimination of ethene and yields elemental selenium and tellurium.
    Permanent Link: http://hdl.handle.net/11104/0063367

     
     

Number of the records: 1  

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