Synthesis and characterization of a manganese(II) complex containing N(sp.sup.2./sup.).sub.4./sub.-donor Schiff base ligand and interaction toward biomacromolecules

0545293 - FZÚ 2022 RIV US eng J - Journal Article
Hakimi, M. - Tarani, B. - Mardani, Z. - Hassani, H. - Kučeráková, Monika - Skořepová, Eliška
Synthesis and characterization of a manganese(II) complex containing N(sp²)₄-donor Schiff base ligand and interaction toward biomacromolecules.
Inorganic and Nano-Metal Chemistry. Roč. 51, č. 11 (2021), s. 1570-1579. ISSN 2470-1556. E-ISSN 2470-1564
R&D Projects: GA ČR(CZ) GA18-10504S; GA MŠMT LM2018110; GA MŠMT(CZ) LO1603
EU Projects: European Commission(CZ) CZ.2.16/3.1.00/24510
Institutional support: RVO:68378271
Keywords : manganese(II) complex * docking study * biomacromolecule * Schiff base * crystal structure
OECD category: Condensed matter physics (including formerly solid state physics, supercond.)
Impact factor: 1.514, year: 2021
Method of publishing: Limited access
https://doi.org/10.1080/24701556.2020.1852250

In this work, an N4-donor Schiff base ligand, N,N'-(propane-1,2-diyl)bis(1-phenyl-1-(pyridin-2-yl)methanimine) (PPPM) and its Mn(II) complex, [Mn(PPPM)(OAc)2].3H2O (1), were prepared and identified by elemental analysis, FT-IR, 1H NMR spectroscopy as well single-crystal X-ray diffraction. X-ray structure analysis of 1 revealed a distorted square-face bicapped trigonal prism geometry around manganese atom with MnN4O4 environment containing an N4-donor PPPM and two O2-donor acetato ligands.
Permanent Link: http://hdl.handle.net/11104/0322160