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Copper, nickel and zinc complexes of a new water-soluble thiosemicarbazone ligand: Synthesis, characterization, stability and biological evaluation
- 1.0485481 - FZÚ 2018 RIV NL eng J - Journal Article
Hosseini-Yazdi, S.A. - Mirzaahmadi, A. - Khandar, A.A. - Mahdavi, M. - Rahimian, A. - Eigner, Václav - Dušek, Michal - Zarrini, G.
Copper, nickel and zinc complexes of a new water-soluble thiosemicarbazone ligand: Synthesis, characterization, stability and biological evaluation.
Journal of Molecular Liquids. Roč. 248, Dec (2017), s. 658-667. ISSN 0167-7322. E-ISSN 1873-3166
R&D Projects: GA ČR(CZ) GA15-12653S; GA MŠMT(CZ) LO1603
EU Projects: European Commission(CZ) CZ.2.16/3.1.00/24510
Institutional support: RVO:68378271
Keywords : cytotoxicity * thiosemicarbazone * water-soluble Schiff base * stability * antioxidant * crystal structure
OECD category: Condensed matter physics (including formerly solid state physics, supercond.)
Impact factor: 4.513, year: 2017
New water soluble Schiff base thiosemicarbazone ligand was obtained by the reaction of methylthiosemicarbazide with sulfonate salicylaldehyde and characterized by elemental analysis, spectroscopic methods and electrospray ionization mass spectrometry. The X-ray structure shows that sodium atoms are interconnected through sulfonate groups of the ligands into one-dimensional coordination polymer network. Reaction of the ligand with metal acetates produced following complexes: [Cu(HL)]2, NiHL and ZnHL. All complexes were characterized by means of elemental analysis, IR spectroscopy, and ESI-Mass measurements.
Permanent Link: http://hdl.handle.net/11104/0280495
Number of the records: 1