Number of the records: 1
Interaction of hydrated protons with octyl-phenyl-N,N-diisobutylcarbamoylmethyl phosphine oxide (CMPO): NMR and theoretical study
- 1.0363834 - ÚMCH 2012 RIV GB eng J - Journal Article
Kříž, Jaroslav - Dybal, Jiří - Makrlík, E. - Vaňura, P.
Interaction of hydrated protons with octyl-phenyl-N,N-diisobutylcarbamoylmethyl phosphine oxide (CMPO): NMR and theoretical study.
Magnetic Resonance in Chemistry. Roč. 49, č. 10 (2011), s. 617-626. ISSN 0749-1581. E-ISSN 1097-458X
R&D Projects: GA ČR GA203/09/1478
Institutional research plan: CEZ:AV0Z40500505
Keywords : CMPO * protonization * dynamic NMR
Subject RIV: CD - Macromolecular Chemistry
Impact factor: 1.437, year: 2011
Interaction of hydronium ions with CMPO was studied in acetonitrile-d3 using 1H, 13C, 31P NMR, PFG NMR and magnetic relaxation. Two complexes with one and two molecules of CMPO per one H3O+ were found to be formed. The dynamics of their exchange was measured by relaxation. The experimental results were confronted with high-precision ab initio DFT calculations.
Permanent Link: http://hdl.handle.net/11104/0199485
Number of the records: 1