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Hydrogenolysis of Carboxylic Ortho Esters
- 1.0561436 - ÚACH 2023 RIV US eng J - Journal Article
Kadyrov, Renat
Hydrogenolysis of Carboxylic Ortho Esters.
Journal of Organic Chemistry. Roč. 87, č. 19 (2022), s. 12673-12676. ISSN 0022-3263. E-ISSN 1520-6904
Institutional support: RVO:61388980
Keywords : Catalysts * Hydrogen * Hydrogenation * Organic compounds * Redox reactions
OECD category: Inorganic and nuclear chemistry
Impact factor: 3.6, year: 2022
Method of publishing: Limited access
https://doi.org/10.1021/acs.joc.2c01116
It is demonstrated for the first time that carboxylic ortho esters may be reduced to acetals using hydrogen as the reducing agent. Hydrogenolysis was performed under mild conditions over commercially available hydrogenation catalysts (5% Pd/C and 5% Pt/C). The present method is especially useful for the selective transformation of carboxylic acids and lactones into acetals.
Permanent Link: https://hdl.handle.net/11104/0334931
Number of the records: 1