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Electrochemical Characterization of Self-Assembled Monolayers Containing Redox Switching Element
- 1.0557929 - ÚFCH JH 2024 RIV CZ eng C - Conference Paper (international conference)
Nováková Lachmanová, Štěpánka - Kocábová, Jana - Vavrek, František - Sebechlebská, Táňa - Šebera, Jakub - Kolivoška, Viliam - Lukášek, J. - Balzer, N. - Valášek, M. - Hromadová, Magdaléna
Electrochemical Characterization of Self-Assembled Monolayers Containing Redox Switching Element.
41. Moderní elektrochemické metody. Sborník přednášek. Ústí nad Labem: Best servis, 2022 - (Navrátil, T.; Fojta, M.; Schwarzová, K.), s. 154-158. ISBN 978-80-905221-9-0.
[Moderní elektrochemické metody /41./. Jetřichovice (CZ), 22.05.2022-26.05.2022]
R&D Projects: GA ČR(CZ) GA21-13458S
Institutional support: RVO:61388955
Keywords : [Ru(terpy)2]2+ * [Os(terpy)2]2+ * Tripodal Anchor * Self-Assembled Monolayer * Electrochemical Impedance Spectroscopy
OECD category: Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)
Adsorption properties of molecules containing [Ru(terpy)2]2+ and [Os(terpy)2]2+ redox switching element connected to the electrode surface by tripodal thiolate anchoring groups have been studied together with their charge transfer properties in the adsorbed form. STM-based current-voltage measurements confirmed that the conductance of self-assembled monolayer containing [Os(terpy)2]2+ redox switching element is lower than that containing [Ru(terpy)2]2+ element. This observation agrees with previously observed differences in the electron transfer rate constants of these molecules in their adsorbed state.
Permanent Link: http://hdl.handle.net/11104/0331820
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Number of the records: 1