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Effect of pulsed methane gas flow on the incorporation of phosphorous in diamond
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SYSNO ASEP 0556046 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Effect of pulsed methane gas flow on the incorporation of phosphorous in diamond Author(s) Mortet, Vincent (FZU-D) RID, ORCID
Taylor, Andrew (FZU-D) RID, ORCID
Davydova, Marina (FZU-D) RID, ORCID
Lamač, Marcel (FZU-D) ORCID
Lambert, Nicolas (FZU-D) ORCID, RID
Elantyev, I. (CZ)
Lorinčík, J. (CZ)
Troadec, D. (FR)
Vronka, Marek (FZU-D) ORCID, RID
Potocký, Štěpán (FZU-D) RID, ORCIDNumber of authors 10 Article number 108928 Source Title Diamond and Related Materials. - : Elsevier - ISSN 0925-9635
Roč. 124, April (2022)Number of pages 6 s. Language eng - English Country CH - Switzerland Keywords diamond ; phosphorus doping ; optical emission spectroscopy ; PECVD Subject RIV BM - Solid Matter Physics ; Magnetism OECD category Condensed matter physics (including formerly solid state physics, supercond.) R&D Projects EF16_019/0000760 GA MŠMT - Ministry of Education, Youth and Sports (MEYS) GA21-03538S GA ČR - Czech Science Foundation (CSF) Research Infrastructure CzechNanoLab - 90110 - Vysoké učení technické v Brně Method of publishing Limited access Institutional support FZU-D - RVO:68378271 UT WOS 000790632900003 EID SCOPUS 85124897543 DOI 10.1016/j.diamond.2022.108928 Annotation The synthesis of n-type phosphorus-doped diamond is essential for the development of diamond-based bipolar devices. Although demonstrated 20 years ago, it remains a complex problem due to low incorporation efficiency and low maximum concentrations. Previous works showed the deleterious influence of methinophosphide formation in a methane/hydrogen/phosphine plasma on the growth of phosphorous doped diamond using the chemical vapor deposition method. In this work, we investigate the effect of pulsing methane during microwave plasma enhanced chemical vapor deposition to avoid the formation of HCP and to increase phosphorus incorporation efficiency and maximum concentration in diamond. Workplace Institute of Physics Contact Kristina Potocká, potocka@fzu.cz, Tel.: 220 318 579 Year of Publishing 2023 Electronic address https://doi.org/10.1016/j.diamond.2022.108928
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