NO and NO2 as non-innocent ligands: A comparison

0518602 - ÚFCH JH 2021 RIV NL eng J - Journal Article
Kaim, W. - Das, A. - Fiedler, Jan - Záliš, Stanislav - Sarkar, B.
NO and NO2 as non-innocent ligands: A comparison.
Coordination Chemistry Reviews. Roč. 404, FEB 2020 (2020), č. článku 213114. ISSN 0010-8545. E-ISSN 1873-3840
Institutional support: RVO:61388955
Keywords : transition-metal-complexes * nitric-oxide * coordination chemistry * oxidation-states * center-dot * ru * generation * reactivity * systems * epr * OFT calculations
OECD category: Physical chemistry
Impact factor: 22.315, year: 2020
Method of publishing: Limited access

The potential of environmentally and technically relevant NO2 for non-innocent ligand behavior in coordination compounds is being evaluated in comparison with the well-studied metal complexes of nitrosyl, NOn (n = +,0,-,2-). A ruthenium semiquinone (Q(center dot-)) radical complex platform [Ru(Q)(L)(NOx)] (x = 1 or 2, L = mer tridentate ligand) can serve to contrast the ligand characteristics of (NO)(n) and (NO2)(n). Strategies to stabilize metal coordinated nitrogen dioxide (as ´nitro´ ligand NO2) versus the well established nitrite NO2- are suggested. (C) 2019 Elsevier B.V. All rights reserved.
Permanent Link: http://hdl.handle.net/11104/0303711