Highly photoactive anatase foams prepared from lyophilized aqueous colloids of peroxo-polytitanic acid

0438977 - ÚACH 2015 RIV NL eng J - Journal Article
Pližingrová, Eva - Volfová, Lenka - Svora, Petr - Labhsetwar, N. - Klementová, Mariana - Szatmáry, Lórant - Šubrt, Jan
Highly photoactive anatase foams prepared from lyophilized aqueous colloids of peroxo-polytitanic acid.
Catalysis Today. Roč. 240, FEB (2015), s. 107-113. ISSN 0920-5861. E-ISSN 1873-4308
R&D Projects: GA ČR(CZ) GA14-20744S
Institutional support: RVO:61388980
Keywords : Anatase * Lyophilization * Photocatalysis * Hydroxyl radical * Peroxo-polytitanic acid foams
Subject RIV: CA - Inorganic Chemistry
Impact factor: 4.312, year: 2015

Peroxo-polytitanic acid foams annealed at temperature above 500 degrees C lose volatile components and excess of oxygen providing anatase in the form of thin leaves consisting of intergrown nanocrystalline anatase particles which transform at temperatures above 850 degrees C to rutile. The size and shape of the initial leaflets forming the foam is preserved up to similar to 900 degrees C. We observed that the annealed material is highly photoactive, owing to highly anisotropic shape of anatase aggregates and their perfect crystallinity. Outstanding photocatalytic activity determined by measuring the kinetics of degradation of Methylene Blue (MB) and 4-chlorphenol (4-CP) as well as measuring the formation of hydroxyl radical spin adducts by EPR spectroscopy was observed. All three methods demonstrated significantly higher activity in comparison with the Degussa P25 photocatalyst. Both methods used for photoactivity tests provided similar results, the activity increased with increasing annealing temperature in order 500 degrees C < Degussa P25 < 600 degrees C< 850-950 degrees C. Results of measurement of formation of center dot OH radicals by EPR also confirmed the unusually high activity of our materials. In comparison with the Degussa P25, the sample annealed at 950 degrees C showed significantly higher production of center dot OH radicals.
Permanent Link: http://hdl.handle.net/11104/0242410