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Sequential formation of N-doped nanohelicenes, nanographenes and nanodomes by surface-assisted chemical (cyclo)dehydrogenation of heteroaromatics

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    0427646 - ÚOCHB 2015 RIV GB eng J - Journal Article
    Pinardi, A. L. - Martínez, J. I. - Jančařík, Andrej - Stará, Irena G. - Starý, Ivo - Lopez, M. F. - Méndez, J. - Martin-Gago, J. A.
    Sequential formation of N-doped nanohelicenes, nanographenes and nanodomes by surface-assisted chemical (cyclo)dehydrogenation of heteroaromatics.
    Chemical Communications. Roč. 50, č. 13 (2014), s. 1555-1557. ISSN 1359-7345. E-ISSN 1364-548X
    R&D Projects: GA ČR(CZ) GAP207/10/2207
    Grant - others:Operational Program Research and Development for Innovations(XE) FP7-604391
    Institutional support: RVO:61388963
    Keywords : dibenzohelicene * UHV-STM * Pt(111)
    Subject RIV: CC - Organic Chemistry
    Impact factor: 6.834, year: 2014

    We report on the stepwise formation of N-doped nanohelicenes, nanographenes, nanodomes and graphenes from the same heteroaromatic precursor through subsequent dehydrogenations on Pt(111) upon thermal annealing. The combined experimental (UHV-STM) and computational (DFT) studies provide a full atomistic description of the intermediate reaction stages.
    Permanent Link: http://hdl.handle.net/11104/0233167

     
     
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