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Molecular Structure Effects in the Asymmetric Transfer Hydrogenation of Functionalized Dihydroisoquinolines on (S,S)-[RuCl(eta (6)-p-cymene)TsDPEN]

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    SYSNO ASEP0425867
    Document TypeJ - Journal Article
    R&D Document TypeJournal Article
    Subsidiary JČlánek ve WOS
    TitleMolecular Structure Effects in the Asymmetric Transfer Hydrogenation of Functionalized Dihydroisoquinolines on (S,S)-[RuCl(eta (6)-p-cymene)TsDPEN]
    Author(s) Václavík, J. (CZ)
    Pecháček, J. (CZ)
    Vilhanová, B. (CZ)
    Šot, P. (CZ)
    Januščák, J. (CZ)
    Matoušek, V. (CZ)
    Přech, J. (CZ)
    Bártová, Simona (MBU-M)
    Kuzma, Marek (MBU-M) ORCID, RID
    Kačer, P. (CZ)
    Source TitleCatalysis Letters - ISSN 1011-372X
    Roč. 143, č. 6 (2013), s. 555-562
    Number of pages8 s.
    Languageeng - English
    CountryUS - United States
    KeywordsATH ; Kinetics ; Imines
    Subject RIVCB - Analytical Chemistry, Separation
    R&D ProjectsGA104/09/1497 GA ČR - Czech Science Foundation (CSF)
    GAP106/12/1276 GA ČR - Czech Science Foundation (CSF)
    Institutional supportMBU-M - RVO:61388971
    UT WOS000318799300006
    DOI10.1007/s10562-013-0996-4
    AnnotationThe asymmetric transfer hydrogenation of five dihydroisoquinolines (DHIQs) was studied by NMR spectroscopy. The DHIQs differed by substitution with methoxy groups, which had a significant effect upon the reaction performance in terms of reaction rate and enantioselectivity. The differences are most probably related to the basicity of DHIQs.
    WorkplaceInstitute of Microbiology
    ContactEliška Spurná, eliska.spurna@biomed.cas.cz, Tel.: 241 062 231
    Year of Publishing2014
Number of the records: 1  

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