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Molecular Structure Effects in the Asymmetric Transfer Hydrogenation of Functionalized Dihydroisoquinolines on (S,S)-[RuCl(eta (6)-p-cymene)TsDPEN]
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SYSNO ASEP 0425867 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Molecular Structure Effects in the Asymmetric Transfer Hydrogenation of Functionalized Dihydroisoquinolines on (S,S)-[RuCl(eta (6)-p-cymene)TsDPEN] Author(s) Václavík, J. (CZ)
Pecháček, J. (CZ)
Vilhanová, B. (CZ)
Šot, P. (CZ)
Januščák, J. (CZ)
Matoušek, V. (CZ)
Přech, J. (CZ)
Bártová, Simona (MBU-M)
Kuzma, Marek (MBU-M) ORCID, RID
Kačer, P. (CZ)Source Title Catalysis Letters - ISSN 1011-372X
Roč. 143, č. 6 (2013), s. 555-562Number of pages 8 s. Language eng - English Country US - United States Keywords ATH ; Kinetics ; Imines Subject RIV CB - Analytical Chemistry, Separation R&D Projects GA104/09/1497 GA ČR - Czech Science Foundation (CSF) GAP106/12/1276 GA ČR - Czech Science Foundation (CSF) Institutional support MBU-M - RVO:61388971 UT WOS 000318799300006 DOI 10.1007/s10562-013-0996-4 Annotation The asymmetric transfer hydrogenation of five dihydroisoquinolines (DHIQs) was studied by NMR spectroscopy. The DHIQs differed by substitution with methoxy groups, which had a significant effect upon the reaction performance in terms of reaction rate and enantioselectivity. The differences are most probably related to the basicity of DHIQs. Workplace Institute of Microbiology Contact Eliška Spurná, eliska.spurna@biomed.cas.cz, Tel.: 241 062 231 Year of Publishing 2014
Number of the records: 1