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Molecular Structure Effects in the Asymmetric Transfer Hydrogenation of Functionalized Dihydroisoquinolines on (S,S)-[RuCl(eta (6)-p-cymene)TsDPEN]
- 1.0425867 - MBÚ 2014 RIV US eng J - Journal Article
Václavík, J. - Pecháček, J. - Vilhanová, B. - Šot, P. - Januščák, J. - Matoušek, V. - Přech, J. - Bártová, Simona - Kuzma, Marek - Kačer, P.
Molecular Structure Effects in the Asymmetric Transfer Hydrogenation of Functionalized Dihydroisoquinolines on (S,S)-[RuCl(eta (6)-p-cymene)TsDPEN].
Catalysis Letters. Roč. 143, č. 6 (2013), s. 555-562. ISSN 1011-372X. E-ISSN 1572-879X
R&D Projects: GA ČR GA104/09/1497; GA ČR GAP106/12/1276
Grant - others:GA MŠk(CZ) LM2010005
Institutional support: RVO:61388971
Keywords : ATH * Kinetics * Imines
Subject RIV: CB - Analytical Chemistry, Separation
Impact factor: 2.291, year: 2013
The asymmetric transfer hydrogenation of five dihydroisoquinolines (DHIQs) was studied by NMR spectroscopy. The DHIQs differed by substitution with methoxy groups, which had a significant effect upon the reaction performance in terms of reaction rate and enantioselectivity. The differences are most probably related to the basicity of DHIQs.
Permanent Link: http://hdl.handle.net/11104/0231660
Number of the records: 1