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Copper(II) acetates with aliphatic/heterocyclic amines - Coupled TG-DTA-EGA study, IR characterization and structure correlation

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    0339816 - ÚACH 2010 RIV HU eng J - Journal Article
    Zeleňák, V. - Vargová, Z. - Györyová, K. - Večerníková, Eva - Balek, V.
    Copper(II) acetates with aliphatic/heterocyclic amines - Coupled TG-DTA-EGA study, IR characterization and structure correlation.
    Journal of Thermal Analysis and Calorimetry. Roč. 82, - (2005), s. 747-754. ISSN 1388-6150. E-ISSN 1588-2926
    Institutional research plan: CEZ:AV0Z40320502
    Keywords : copper acetate * 1,3-diaminopropane * DTA
    Subject RIV: CA - Inorganic Chemistry
    Impact factor: 1.425, year: 2005

    Three copper acetate complex compounds, namely Cu(CH3COO)(2)(en)(2)center dot 2H(2)O (I), Cu(CH3COO)(2)(tn)(2)(II) and Cu-2(CH3COO)(4)(pyz) (III) (en=ethylenediamine, tn=1,3-diaminopropane, pyz=pyrazine), were prepared and characterized during heating in argon by thermogravimetry (TG), differential thermal analysis (DTA) and evolved gas analysis (EGA) using mass spectrometry (MS). The results of infrared spectroscopy (IR) were evaluated to be used as a spectroscopic criterion for the determination of the carboxylate binding mode in the compounds.
    Permanent Link: http://hdl.handle.net/11104/0183230

     
     
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