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Dielectric Spectroscopy of Calcium Titanate Processed by Spark Plasma Sintering
- 1.0583097 - ÚFP 2024 RIV CH eng J - Journal Article
Ctibor, Pavel - Sedláček, J. - Straka, L. - Lukáč, František - Neufuss, Karel
Dielectric Spectroscopy of Calcium Titanate Processed by Spark Plasma Sintering.
Materials. Roč. 16, č. 3 (2023), č. článku 975. ISSN 1996-1944. E-ISSN 1996-1944
Institutional support: RVO:61389021
Keywords : band gap * calcium titanate * dielectrics * permittivity * spark plasma sintering
OECD category: Materials engineering
Impact factor: 3.1, year: 2023
Method of publishing: Open access
https://www.mdpi.com/1996-1944/16/3/975
Calcium titanate (CaTiO3) powder was compacted by spark plasma sintering (SPS). The resulting products were subjected to the phase stability study and dielectric characterization. The change in temperature of SPS between 1100 °C and 1250 °C had a clear and straightforward effect on density, porosity, relative permittivity, loss tangent, and DC resistivity. Since the SPS itself introduces certain oxygen deficiency into Ti-perovskites, all samples were annealed after SPS. However, this post-processing did not mask the effects of the SPS regime. Optical reflectance measurements were completed to compare and quantify the sample coloration and support the dielectric results with corresponding optical band gap estimations. Subtle changes in the CaTiO3 crystal lattice arrangement, completed between 1150 °C and 1250 °C and documented in the literature for conventionally sintered samples, could not be confirmed for SPS-prepared calcium titanate. The novelty of this research work is in producing very stable dielectric ceramics and an indication of the SPS processing parameters suitable for this. The best sample showed at 1 MHz frequency the combination of relative permittivity 370, loss tangent 0.008, and DC resistivity 3 × 1012 Ωm.
Permanent Link: https://hdl.handle.net/11104/0351094
Number of the records: 1