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The thermodynamic reassessment of the binary Al–Cu system
- 1.0534273 - ÚFM 2021 RIV US eng J - Journal Article
Kroupa, Aleš - Zobač, Ondřej - Richter, K. W.
The thermodynamic reassessment of the binary Al–Cu system.
Journal of Materials Science. Roč. 56, č. 4 (2020), s. 3430-3443. ISSN 0022-2461. E-ISSN 1573-4803
Institutional support: RVO:68081723
Keywords : Al-Cu system * thermodynamic modelling * CALPHAD * DSC/DTA * SEM–EDX
OECD category: Thermodynamics
Impact factor: 4.220, year: 2020
Method of publishing: Limited access
https://link.springer.com/article/10.1007%2Fs10853-020-05423-7
The Al–Cu binary system has been investigated intensively in the past as key binary system for many important industrial alloys. With respect to new experimental results about phase equilibria in Al–Cu system, it was found necessary to prepare new CALPHAD-type thermodynamic description of the Al–Cu system. In course of this work, the known crystallography of several intermetallic phases and the information about site occupations in particular crystallographic positions were implemented in the new thermodynamic phase descriptions. The intermetallic phases were furthermore modelled with all their different temperature modifications. Very good agreement with the experimental results was reached both, for the Al–Cu phase diagram and for the calculated thermodynamic properties, namely the enthalpy of mixing, enthalpies of formation and thermodynamic activities.
Permanent Link: http://hdl.handle.net/11104/0312532
Number of the records: 1